Alkalinity, Major and Trace Elements as Hydrological Tracers in Different Seasons: Implications for the Origin of Hot Springs in Non-Volcanic Areas, Odisha, India

Authors

  • Snehal V Dewalkar Department of Civil Engineering, Sinhgad Academy of Engineering, Pune, Maharashtra
  • Nishant Shinde Department of Civil Engineering, Sinhgad Academy of Engineering, Pune, Maharashtra
  • Manmeet Kaur Bharti Vishwavidyalaya, Durg, Chhattisgarh
  • Prabhjot Singh Bhuie Bharti Vishwavidyalaya, Durg, Chhattisgarh
  • Arti Hadap Department of Basic Science and Humanities, NMIMS's Mukesh Patel School of Technology Management & Engineering
  • Shivmurti B Kshetri K .J. College of Engineering and Research

DOI:

https://doi.org/10.58524/ijhes.v3i3.518

Keywords:

alkalinity, hydrological tracers, major elements, trace elements, hot springs, non-volcanic areas, different seasons

Abstract

During the rainy season, surface water can infiltrate and mix with groundwater, making it difficult to identify different groundwater sources. In addition, mixing of water from different sources over time can obscure the original characteristics of groundwater. In this study, we used geochemical analyses such as alkalinity, major elements, hydrological modelling and long-term monitoring before, during and after the rainy season to understand the changes in concentrations, and determine the origin of groundwater sources despite different seasonal conditions. The data from this study was taken from a previous study and examined 18 water samples with different locations and weather conditions. Determination of 9 elements including alkalinity and trace elements was conducted as the main elements in this study. In the experiment, water temperature, pH, alkalinity, and free CO content were measured in situ from non-volcanic hot water, Odisha, India. In the process, the water was put into two polypropylene bottles, and cation and anion analyses were conducted in the laboratory. The results showed that seasonal differences clearly affected the changes in alkalinity concentration of each hot spring. However, hot springs with higher alkalinity experienced larger changes. In contrast, the analysed chlorine (Cl) concentrations < 100 mg/L were more susceptible to shifts due to monsoon, whereas Cl concentrations > 100 mg/L were more homogeneous despite the influence of monsoon (seasonal differences). Differences in the rainy season affected the concentration changes in Attri, Tarabalo and Deulajhari hot springs. Meanwhile, hot springs dominated by meteoric water such as Badaberena, Taptapani and Boden are less affected. This proves that Attri, Tarabalo and Deulajhari hot springs originate and are dominated by deep groundwater.

References

Acharya, S., Sharma, S. K., & Khandegar, V. (2018). Assessment of groundwater quality by water quality indices for irrigation and drinking in South West Delhi, India. Data in Brief, 18(2018), 2019–2028. https://doi.org/10.1016/j.dib.2018.04.120

Adejumo, R. O., Adagunodo, T. A., Bility, H., Lukman, A. F., & Isibor, P. O. (2018). Physicochemical constituents of groundwater and its quality in crystalline bedrock, Nigeria. International Journal of Civil Engineering and Technology, 9(8), 887–903.

Adimalla, N., & Venkatayogi, S. (2018). Geochemical characterization and evaluation of groundwater suitability for domestic and agricultural utility in semi-arid region of Basara, Telangana State, South India. Applied Water Science, 8(1), 44. https://doi.org/10.1007/s13201-018-0682-1

Adji, T. N., Haryono, E., Fatchurohman, H., & Oktama, R. (2016). Diffuse flow characteristics and their relation to hydrochemistry conditions in the Petoyan Spring, Gunungsewu Karst, Java, Indonesia. Geosciences Journal, 20(3), 381–390. https://doi.org/10.1007/s12303-015-0048-8

Al-Khashman, O. A., Alnawafleh, H. M., Jrai, A. M. A., & Al-Muhtaseb, A. H. (2017). Monitoring and Assessing of Spring Water Quality in Southwestern Basin of Jordan. Open Journal of Modern Hydrology, 07(04), 331–349. https://doi.org/10.4236/ojmh.2017.74019

Blanchette, D., Lefebvre, R., Nastev, M., & Cloutier, V. (2010). Groundwater quality, geochemical processes and groundwater evolution in the Chateauguay River watershed, Quebec, Canada. Canadian Water Resources Journal, 35(4), 503–526. https://doi.org/10.4296/cwrj3504503

Brindha, K., & Elango, L. (2012). Groundwater quality zonation in a shallow weathered rock aquifer using GIS. Geo-Spatial Information Science, 15(2), 95–104. https://doi.org/10.1080/10095020.2012.714655

Dhaka, S. K., & Bhaskar, N. (2017). Assessment of Ground Water Quality in Terms of Water Quality Index and Regression Analysis of Water Quality Parameters. Journal of Basic and Applied Engineering Research, 4(4), 339–342.

Dragon, K., & Marciniak, M. (2010). Chemical composition of groundwater and surface water in the Arctic environment (Petuniabukta region, central Spitsbergen). Journal of Hydrology, 386(1–4), 160–172. https://doi.org/10.1016/j.jhydrol.2010.03.017

Guo, Q., & Wang, Y. (2012). Geochemistry of hot springs in the Tengchong hydrothermal areas, Southwestern China. Journal of Volcanology and Geothermal Research, 215–216, 61–73. https://doi.org/10.1016/j.jvolgeores.2011.12.003

Haines, S. H., & van der Pluijm, B. A. (2012). Patterns of mineral transformations in clay gouge, with examples from low-angle normal fault rocks in the western USA. Journal of Structural Geology, 43, 2–32. https://doi.org/10.1016/j.jsg.2012.05.004

Huh, Y., Chan, L. H., Zhang, L., & Edmond, J. M. (1998). Lithium and its isotopes in major world rivers: implications for weathering and the oceanic budget. Geochimica et Cosmochimica Acta, 62(12), 2039–2051. https://doi.org/10.1016/S0016-7037(98)00126-4

Iqbal, M., & Kusumasari, B. A. (2024). Deciphering the Way Ratai geothermal system, Lampung, Indonesia: A comprehensive geochemical and isotopic analysis. Geothermics, 119. https://doi.org/10.1016/j.geothermics.2024.102985

Jamal, N., & Singh, N. P. (2018). Identification of fracture zones for groundwater exploration using very low frequency electromagnetic (VLF-EM) and electrical resistivity (ER) methods in hard rock area of Sangod Block, Kota District, Rajasthan, India. Groundwater for Sustainable Development, 7, 195–203. https://doi.org/10.1016/j.gsd.2018.05.003

Javino, F., Suratman, S., Pang, Z., Choudhry, M. A., Caranto, J., Ogena, M., & Amnan, I. (2010). Isotope and Geochemical Investigations on Tawau Hot Springs in Sabah, Malaysia. Proceedings World Geothermal Congress, 25–29.

Kazahaya, K., Takahashi, M., Yasuhara, M., Nishio, Y., Inamura, A., Morikawa, N., … Kirita, T. (2014). Spatial distribution and feature of slab-related deep-seated fluid in SW Japan. The Japan Society of Hydrology and Water Resources, 44(1), 3–16.

Khan Adnan, & Rehman Yusra. (2017). Groundwater quality assessment using water quality index (WQI) in Liaquatabad Town. Academia Journal of Environmental Science, 5(6), 95–101.

Kumar, R., & Yadav, G. S. (2015). Delineation of fracture zones in the part of Vindhyan fringe belt of Ahraura region, Mirzapur district, Uttar Pradesh, India using integrated very low frequency electromagnetic and resistivity data for groundwater exploration. Arabian Journal of Geosciences, 8(2), 727–737. https://doi.org/10.1007/s12517-014-1283-4

Kumar, S. K., Rammohan, V., Sahayam, J. D., & Jeevanandam, M. (2009). Assessment of groundwater quality and hydrogeochemistry of Manimuktha River basin, Tamil Nadu, India. Environmental Monitoring and Assessment, 159(1–4), 341–351. https://doi.org/10.1007/s10661-008-0633-7

Kusuhara, F., Kazahaya, K., Morikawa, N., Yasuhara, M., Tanaka, H., Takahashi, M., & Tosaki, Y. (2020). Original composition and formation process of slab-derived deep brine from Kashio mineral spring in central Japan. Earth, Planets and Space, 72(1). https://doi.org/10.1186/s40623-020-01225-y

Lin, J. Y., Sibuet, J. C., Hsu, S. K., & Wu, W. N. (2014). Could a Sumatra-like megathrust earthquake occur in the south Ryukyu subduction zone? Earth, Planets and Space, 66(1), 1–8. https://doi.org/10.1186/1880-5981-66-49

McConnell, M. C., Thunell, R. C., Lorenzoni, L., Astor, Y., Wright, J. D., & Fairbanks, R. (2009). Seasonal variability in the salinity and oxygen isotopic composition of seawater from the Cariaco Basin, Venezuela. Geochemistry, Geophysics, Geosystems, 10(6). https://doi.org/10.1029/2008GC002035

Meredith, K., Moriguti, T., Tomascak, P., Hollins, S., & Nakamura, E. (2013a). The lithium, boron and strontium isotopic systematics of groundwaters from an arid aquifer system. Geochimica et Cosmochimica Acta, 112, 20–31. https://doi.org/10.1016/j.gca.2013.02.022

Meredith, K., Moriguti, T., Tomascak, P., Hollins, S., & Nakamura, E. (2013b). The lithium, boron and strontium isotopic systematics of groundwaters from an arid aquifer system. Geochimica et Cosmochimica Acta, 112, 20–31. https://doi.org/10.1016/j.gca.2013.02.022

Millot, R., Hegan, A., & Négrel, P. (2012). Geothermal waters from the Taupo Volcanic Zone, New Zealand: Li, B and Sr isotopes characterization. Applied Geochemistry, 27(3), 677–688. https://doi.org/10.1016/j.apgeochem.2011.12.015

Muthamilselvan, A., Rajasekaran, N., & Suresh, R. (2019). Mapping of hard rock aquifer system and artificial recharge zonation through remote sensing and GIS approach. Journal of Groundwater Science and Engineering, 7(3), 264–281.

Purnomo, B. J., Pichler, T., & You, C. F. (2016). Boron isotope variations in geothermal systems on Java, Indonesia. Journal of Volcanology and Geothermal Research, 311, 1–8. https://doi.org/10.1016/j.jvolgeores.2015.12.014

Tang, Y. J., Zhang, H. F., & Ying, J. F. (2007). Review of the lithium isotope system as a geochemical tracer. International Geology Review, 49(4), 374–388. https://doi.org/10.2747/0020-6814.49.4.374

Umam, R., Tanimizu, M., Nakamura, H., Nishio, Y., Nakai, R., Sugimoto, N., … Ishikawa, T. (2022). Lithium isotope systematics of Arima hot spring waters and groundwaters in Kii Peninsula. Geochemical Journal, 56(5), E8–E17. https://doi.org/10.2343/geochemj.GJ22015

Zhu, H., Tan, H., Cong, P., & Shi, Z. (2025). Sources and Enrichment Mechanisms of Li-Rich Geothermal Springs in the Mediterranean-Himalayan Belt. Geological Journal, 2019–2032. https://doi.org/10.1002/gj.5134

Downloads

Published

2024-12-12

How to Cite

Dewalkar, S. V., Shinde, N., Kaur, M., Bhuie, P. S., Hadap, A., & Kshetri, S. B. (2024). Alkalinity, Major and Trace Elements as Hydrological Tracers in Different Seasons: Implications for the Origin of Hot Springs in Non-Volcanic Areas, Odisha, India. International Journal of Hydrological and Environmental for Sustainability, 3(3), 126-137. https://doi.org/10.58524/ijhes.v3i3.518